|
KMID : 0380620100420030277
|
|
Korean Journal of Food Science and Technology
2010 Volume.42 No. 3 p.277 ~ p.280
|
|
|
Decreased Stability of Bisphenol A by Photosensitization
|
|
Park Chan-Uk
Lee Jae-Hwan
|
|
|
Abstract
|
|
|
|
Bisphenol A (BPA) is an endocrine disruptor frequently used in food containers, including epoxy resin and polycarbonates. BPA concentrations were monitored by high performance liquid chromatography (HPLC) under photosensitization of riboflavin (RF), methylene blue (MB), rose bengal (RB), or titanium dioxide (TiO2) and the involvement of singlet oxygen was determined using sodium azide (NaN3). The stability of BPA decreased significantly in the order of RF, RB, and MB photosensitization (p<0.05), while the concentration of BPA in samples with TiO2 was not significantly different from that of control samples without photosensitizers under light (p>0.05). The stability of BPA decreased in an MB concentration-dependent manner and increased as the concentration of added NaN3 increased, implying that singlet oxygen was involved in the photodegradation of BPA during MB photosensitization. The results of this study may help control the BPA content in foods or the environments using photosensitized oxidation and visible light irradiation.
|
|
|
KEYWORD
|
|
|
bisphenol A, photosensitization, singlet oxygen, methylene blue
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|